Preheat the oven to 400°F and lightly grease a large sheet pan or line it with parchment paper for easier cleanup.
Pat the pork chops dry with paper towels and set aside.
In a bowl, whisk together the garlic, soy sauce, sesame oil, olive oil, honey, rice vinegar, black pepper, water, and cornstarch until smooth.
Add the pork chops, bell peppers, ginger, dried chilies, and peanuts to the sheet pan.
Pour the sauce over everything and gently toss so the pork chops and vegetables are coated.
Bake for 12–15 minutes, spooning some of the sauce over the pork chops halfway through cooking.
Switch the oven to broil for the last 1–2 minutes to help caramelize the sauce and lightly brown the pork chops.
Serve over rice and top with chopped green onions before serving.